Ring-Opening Polymerization of Ethylene Oxide Initiated by Sodium Methoxide 甲醇钠引发的环氧乙烷开环聚合反应过程
In the function of sodium methoxide, several factors effecting on alcoholysis of urea by zinc oxide catalyst were obtained. 探讨了在甲醇钠作用下,氧化锌催化尿素醇解的影响因素。
Compared with the activity of sodium methoxide, sodium ethoxide, sodium isopropyl, sodium tert-butoxide, The best base catalyst was sodium tert-butoxide. 比较甲醇钠、乙醇钠、异丙醇钠和叔丁醇钠催化活性,叔丁醇钠为最佳的催化剂。
Sodium methoxide used as catalyst for the synthesis of methyl formate by carbonylation of methanol was studied, and effect of three kinds of promoter was investigated. 在间歇釜式反应器中,进行一氧化碳与甲醇羰基化合成甲酸甲酯的合成,考察甲醇钠碱性催化体系对反应的影响。
By reacting isobutyraldehyde with diethyl oxalate using sodium methoxide as catalyst, 3-methyl-2-oxobutanoic acid, sodium salt was prepared by one pot. 采用甲醇钠催化异丁醛与草酸二乙酯反应,一釜法合成了3-甲基-2-氧代丁酸钠。
Replacement of potassium hydride by sodium methoxide, replacement of hydrogen chloride by HCl-ethanol, and replacement of ether by toluene were in the improved procedure. 以甲醇钠代替氢化钾作为缩合剂,以盐酸乙醇代替氯化氢气体,以甲苯代替乙醚,对此工艺进行了改进。
Budgetary estimate for the 600 t/ a synthesizing sodium methoxide with metal sodium, revenue and profit were calculated. 并对抚顺市化工研究设计院600t/a金属钠法合成甲醇钠装置项目进行了概算,同时计算了装置的税收及利润,最后分析了企业的盈利能力和偿债能力。
The recovered methanol, with water content less than 0.02%, from the condensation effluent in a methanol tower with 40 theoretical plates and a reflux ratio of 3 can be reused to prepare sodium methoxide. 结果表明,缩合废液甲醇塔回流比为3,理论板为40时,回收甲醇中水的质量分数可降至0.02%,可复用于生产甲醇钠。
Chemistry analysis of sodium methoxide and sodium formate 甲醇钠和甲酸钠的化学分析
Results and conclusions The proportion of 1-methyl-1-thiosemicarbazide, oxalic diacetate and sodium methoxide was 1.0 ∶ 1.1 ∶ 2.0, and the yield was 60% under the suitable reaction condition. 结果及结论适宜的反应条件为1-甲基-1-氨基硫脲、草酸二乙酯、甲醇钠的量(摩尔)比例为10∶11∶20,其收率可达60%。
We investigated relationships between the reaction and concentration of sodium methoxide or temperature by XRD analysis. 利用XRD为主要检测手段研究了甲醇钠的质量分数、反应温度等因素对反应的影响。
Determination of Content of Sodium Methoxide and Its Solubility in Tetrahydrofuran by Micro-titration 微量滴定法测定甲醇钠含量及其在四氢呋喃中的溶解度
A new method of preparing intercalated and amorphous kaolinite with sodium methoxide was introduced in this article. 利用甲醇钠强烈的夺氢作用,介绍了一种制备插层和无定形高岭土的方法。
The supported alkaline catalysts were prepared using triethylamine and sodium methoxide as active components and using A, X and Y type molecular sieves, silica and organic polymer carriers as supports. 以三乙胺和甲醇钠为活性碱组分,以A,X和Y型分子筛及硅胶和有机高聚物担体为载体制备了负载型碱性催化剂。
Tetrabutyl ammonium bromide and sodium methoxide were used as catalyst for the reaction. 四丁基溴化铵和甲醇钠构成该反应的双组份催化剂。
Synthesis of methyl formate ( MF) by carbonylation of methanol with only sodium methoxide as catalyst exists some shortages, such as low activity, rapid loss of activity and short catalyst life. 以单一甲醇钠作为催化剂通过甲醇羰基合成甲酸甲酯,存在催化剂活性不高、易失活、寿命短等问题。
An improved method of synthesizing trimethyl orthoformate through azeotropic distillation by taking sodium methoxide in methanol and chloroform as raw materials has been presented by the author. 介绍了以甲醇钠甲醇溶液与氯仿为原料,采用共沸蒸馏法制备原甲酸三甲酯的改进工艺。
In this paper, Nitrobenzene, m-Nitrobenzoic acid, p-Nitrobenzoic acid were aminated by Vicarious Nucleophilic Substitution of hydrogen, using 4-amino-1,2,4-triazole in sodium methoxide and dimethylsulfoxide at normal temperature and pressure. 本文采用4-氨基-1,2,4-三唑为胺化剂,在甲醇钠和二甲基亚砜中对硝基苯、间硝基苯甲酸、对硝基苯甲酸进行VNS直接胺化来合成芳胺。
The Exchange Reaction of α-Hydroxyisobutyric Acid Amide and Methyl Formate Catalyzed by Sodium Methoxide 甲醇钠催化的α-羟基异丁酰胺与甲酸甲酯的交换反应
The status of R& D on methanol synthesis catalyst was reviewed. Sodium methoxide was used as the catalyst in the thermal decomposition of isatin 3-oxime, and tetramethylene sulfone was used as the solvent. 靛红3肟的热分解催化剂为甲醇钠,环丁砜用作溶剂。
Structural changes of kaolinite in sodium methoxide solution were characterized by XRD, IR and TEM measurements. 利用XRD、IR和TEM分析了高岭石结构的变化。
The catalytic system propylene oxide ( PO) promoted sodium methoxide ( MeONa) used for methanol carbonylation to methyl formate ( MF) in the liquid phase has been studied and reported. 报道环氧丙烷(PO)助催的甲醇钠催化剂体系用于甲醇的液相催化羰基化制取甲酸甲酯(MF)反应。
In recent years, the demand for sodium methoxide has been increasing in medicine and pesticide in China, so the expansion of sodium methoxide production is imperative. 近年,国内医药、农药对甲醇钠需求量持续增加,因此甲醇钠生产的扩建已经是势在必行。
The reaction in the Deacetylation was carried out in methanol/ sodium methoxide system. The synthesis method was better than other methods with the mild reaction conditions, simple and three-dimensional post-processing advantages such as selectivity, and the relatively higher production rate. 脱乙酰反应是在甲醇钠/甲醇体系中进行的,该合成方法同其他方法相比具有反应条件温和,后处理简单和立体选择性强等优点,且产率也相对较高。
The alkaline process of sodium methoxide of chemical industry has many hazardous factors. 碱法甲醇钠的生产属于化工行业,在生产中有许多危险因素。